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Chemical oxygen demand : ウィキペディア英語版
Chemical oxygen demand
In environmental chemistry, the chemical oxygen demand (COD) test is commonly used to indirectly measure the amount of organic compounds in water. Most applications of COD determine the amount of organic pollutants found in surface water (e.g. lakes and rivers) or wastewater, making COD a useful measure of water quality. It is expressed in milligrams per liter (mg/L), which indicates the mass of oxygen consumed per liter of solution.
==Overview==
The basis for the COD test is that nearly all organic compounds can be fully oxidized to carbon dioxide with a strong oxidizing agent under acidic conditions. The amount of oxygen required to oxidize an organic compound to carbon dioxide, ammonia, and water is given by:
:\mbox_n\mbox_a\mbox_b\mbox_c + \left( n + \frac - \frac - \fracc \right)\mbox_2 \rightarrow n\mbox_2 + \left( \frac - \fracc \right)\mbox_2\mbox + c\mbox_3
This expression includes the oxygen demand caused by the oxidation of ammonia into nitrate. The process of ammonia being converted into nitrate is referred to as ''nitrification.'' The following is the correct equation for the oxidation of ammonia into nitrate.
:\mbox\mbox_3 + 2\mbox_2 \rightarrow \mbox\mbox_3^- + \mbox_3\mbox^+
It is applied after the oxidation due to nitrification if the oxygen demand from nitrification must be known. Dichromate does not oxidize ammonia into nitrate, so this nitrification can be safely ignored in the standard chemical oxygen demand test.
The International Organization for Standardization describes a standard method for measuring chemical oxygen demand in ISO 6060 ().

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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